1:暨南大学先进耐磨蚀及功能材料研究院
摘要(Abstract):
针对Zn-Ni镀层耐磨性不足的问题,采用脉冲电沉积技术制备Zn-Ni-PTFE复合镀层,系统探究占空比、平均电流密度对Zn-Ni-PTFE复合镀层组织结构、PTFE复合量以及力学与摩擦学性能的影响。结果表明,占空比降低可提高PTFE复合量,当占空比为12.5%、电流密度为1 A/dm~2条件下制备的复合镀层的PTFE复合量最高达到28.47%(体积分数),水接触角达到了最高的139.6°;在占空比为12.5%、电流密度为2 A/dm~2条件下制备的复合镀层磨损率最低为3.2×10~(-8) mm~3/(N·m),其摩擦系数在摩擦过程中稳定维持在0.11。高电流密度(>4 A/dm~2)导致PTFE复合量骤减,镀层裂纹增多,润滑功能失效。在摩擦过程中镀层以磨粒磨损和疲劳磨损为主,PTFE补充机制可延缓摩擦系数上升,实现长效润滑。
关键词(KeyWords): 脉冲电沉积;Zn-Ni-PTFE复合镀层;参数调控;耐磨性能
基金项目(Foundation): 国家重点研发计划项目,高稳定绿色化电镀工艺技术与成套装备,2023YFB3408200~~
作者(Author): 陈文婷,王启伟,阳颖飞,杨俊杰,曹琳,张鹏
DOI: 10.26935/j.issn.2097-5317.2025.0012
参考文献(References):
[1] JEONG H I,PARK M Y,YOO U J,et al.A study on the mechanical properties of forged high chrome steel heat resistant materials[J].Modern Physics Letters B,2020,34(7-9):5.
[2] SUNDARAMALI G,AIYASAMY J P,KARTHIKEYAN S,et al.Experimental investigations of electrodeposited Zn-Ni,Zn-Co,and Ni-Cr-Co-based novel coatings on AA7075 substrate to ameliorate the mechanical,abrasion,morphological,and corrosion properties for automotive applications[J].Reviews on Advanced Materials Science,2023,62(1):20220324.
[3] OLIVEIRA R P,BERTAGNOLLI D C,DA S L,et al.Effect of Fe and Co co-deposited separately with Zn-Ni by electrodeposition on ASTM A624 steel[J].Applied Surface Science,2017,420:53-62.
[4] KAFRI A,OVADIA S,YOSAFOVICH-DOITCH G,et al.In vivo performances of pure Zn and Zn-Fe alloy as biodegradable implants[J].Journal of Materials Science:Materials in Medicine,2018,29:1-8.
[5] LI B,LI D,XIA W,et al.Synthesis and characterization of a novel Zn-Ni and Zn-Ni/Si3N4 composite coating by pulse electrodeposition[J].Applied Surface Science,2018,458:665-677.
[6] BHAT R S,SHET V B.Development and characterization of Zn-Ni,Zn-Co and Zn-Ni-Co coatings[J].Surface Engineering,2020,36(4):429-437.
[7] ROUSSE C,BEAUFILS S,FRICOTEAUX P.Electrodeposition of Cu-Zn thin films from room temperature ionic liquid[J].Electrochimica Acta,2013,107:624-631.
[8] BHAT R S,SHET V B.Development and characterization of Zn-Ni,Zn-Co and Zn-Ni-Co coatings[J].Surface Engineering,2020,36(4):429-437.
[9] KERMOUNE H,LEVESQUE A,DOUGLAD J,et al.Magnetic field effect on Zn-Co alloy electroplating[J].Ionics,2017,23(12):3 565-3 570.
[10] KWON M,JO D,CHO S H,et al.Characterization of the influence of Ni content on the corrosion resistance of electrodeposited Zn-Ni alloy coatings[J].Surface and Coatings Technology,2016,288:163-170.
[11] 谢海婷,罗翔,贾丽君.Zn-Ni/PTFE复合镀层制备及其在模拟污水中的耐腐蚀与阻垢性能[J].电镀与精饰,2023,45(9):15-22.XIE H T,LUO X,JIA L J.Preparation of Zn-Ni/PTFE composite coatings and their corrosion resistance and scale inhibition performance in simulated wastewater[J].Plating and Finishing,2023,45(9):15-22.
[12] HUANG C,ZHANG Z,SUN L,et al.Enhancing wear and corrosion resistance of electroless Ni-P coatings in CO2-saturated NaCl solution through polytetrafluoroethylene incorporation[J].Corrosion Science,2024,226:111620.
[13] IACOVETTA D,TAM J,ERB U.Synthesis,structure,and properties of superhydrophobic nickel-PTFE nanocomposite coatings made by electrodeposition [J].Surface and Coatings Technology,2015,279:134-141.
[14] SANGEETHA S,KALAIGNAN G P,ANTHUVAN J T.Pulse electrodeposition of self-lubricating Ni-W/PTFE nanocomposite coatings on mild steel surface [J].Applied Surface Science,2015,359:412-419.
[15] TAFRESHI M,ALLAHKARAM S R,MAHDAVI S.Effect of PTFE on characteristics,corrosion,and tribological behavior of Zn-Ni electrodeposits [J].Surface Topography:Metrology and Properties,2020,8(4):045013.
[16] WASEKAR N P,LATHA S M,RAMAKRISHNA M,et al.Pulsed electrodeposition and mechanical properties of Ni-W/SiC nano-composite coatings[J].Materials & Design,2016,112:140-150.
[17] YOOSEFAN F,ASHRAFI A,MONIRV S M,et al.Synthesis of CoCrFeMnNi high entropy alloy thin films by pulse electrodeposition:Part 1:Effect of pulse electrodeposition parameters[J].Metals and Materials International,2020,26:1 262-1 269.
[18] 安茂忠,杨培霞,张锦秋.现代电镀技术[M].北京:机械工业出版社,2018.AN M Z,YANG P X,ZHANG J Q.Modern Electroplating Technology [M].Beijing:China Machine Press,2018.
[19] 屠振密,李宁,胡会利,等.电沉积纳米晶材料技术[M].北京:国防工业出版社,2008.TU Z M,LI N,HU H N,et al.Technology of Electrodeposited Nanocrystalline Materials [M].Beijing:National Defense Industry Press,2008.
[20] HANSAL W E G,SANDULACHE G,MANN R,et al.Pulse-electrodeposited NiP-SiC composite coatings[J].Electrochimica Acta,2013,114:851-858.
[21] RAMAPRAKASH M,DEEPIKA Y,BALAMURUGAN C,et al.Pulse electrodeposition of nano-crystalline Ni-W alloy and the influence of tungsten composition on structure,microhardness and corrosion properties[J].Journal of Alloys and Compounds,2021,866:158987.
[22] TAM J,PALUMBO G,ERB U.Recent Advances in Superhydrophobic Electrodeposits [J].Materials (Basel),2016,9(3):151.
[23] KARSLIOGLU R,AKBULUT H.Comparison microstructure and sliding wear properties of nickel-cobalt/CNT composite coatings by DC,PC and PRC current electrodeposition [J].Applied Surface Science,2015,353:615-627.
[24] 张玉碧,高小丽,王东哲,等.脉冲电沉积机理、动力学分析及其验证[J].材料保护,2011(6):18-21.ZHANG Y B,GAO X L,WANG D Z,et al.Analysis of Mechanism and Dynamics for Pulse Electrodeposition and Its Verification[J].Materials Protection,2011(6):18-21.
[25] 焦立苗.PbO2-CeO2纳米复合电极的脉冲电沉积制备与电催化降解性能的研究[D].天津:河北工业大学,2016.JIAO L M.Preparation and Electrocatalytic Properties of PbO2-CeO2 Nanocomposite Electrodes by Pulse Electrodeposition Methods[D].Tianjin:Hebei University of University,2016.
[26] ISERN L,IMPEY S,ALMOND H,et al.PTFE layer formation during brush electroplating of nickel[J].Scientific Reports,2024,14(1):24069.